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NASA strives to create the best and safest battery with SABERS



NASA strives to create the best and safest battery with SABERS

Powering the electric planes of tomorrow like the one shown in this illustration will require new battery designs that are safer than today’s models. NASA’s SABERS research project is testing new ways to combine familiar and exotic materials to create a more advanced battery. Credit: NASA

Solving battery problems on our phones, tablets or laptops can be frustrating.

Although batteries are everywhere in everyday life, many still fail and fail. The slight inconvenience associated with more frequent charging can even result in costly repairs or the purchase of a new device altogether. The batteries in larger electronics like hoverboards or cars can even catch fire.

Now that more and more attention is being paid to the sustainability of aviation, interest in using batteries to partially or fully power electrical propulsion systems in aircraft of all sizes is growing every day.

So the question is, is there a better way to create batteries that are completely safe and won’t break or even catch fire?

BUT NASA an activity called SABERS, or “Solid state batteries for increased rechargeability and safetyExplores how to create a safer battery using entirely new materials and new construction methods.

The goal is to create a battery that has significantly higher energy than the lithium-ion batteries we currently use. This battery also won’t lose capacity over time, catch fire or endanger passengers if something goes wrong.

“Rather than taking a battery off the shelf, we decided we needed to design a battery from scratch that would be tailored to the unique performance requirements of an electric aircraft,” said Rocco Vigiano, SABERS lead researcher at NASA’s Glenn Research Center in Cleveland.

It turns out that solid state batteries fit the bill.

Unlike many modern batteries, the batteries SABERS wants to create do not contain liquid in their design. An all-solid battery is less complex in packaging, reduces safety risks, and can withstand more damage than a battery with a liquid inside.

The project explored the use of a unique combination of the elements sulfur and selenium to contain an electrical charge.

“The solid-state sulfur-selenium battery is cool to the touch and does not burn. It has a slimmer profile than lithium-ion batteries and has better energy retention. He can withstand the beatings and still work, often in less than ideal conditions, ”said Vigiano.

An additional benefit is that sulfur is a by-product of refining. There are stocks of this element all over the world that are available and are just waiting to be used. With a little imagination, this waste can be turned into something that can be used in environmentally friendly vehicles.

Imagination is another aspect of SABERS.

The project aims to use elements that have never been combined to form a battery before. For example, a component developed by NASA called “leaky” graphene”(Named for the holes in its surface through which air passes) has a very high level of electrical conductivity. It is ultra lightweight and environmentally friendly.

“This material has never been used in battery systems and we are combining it with other materials that have never been used,” said Vigiano.

SABERS is making great strides

Solid state batteries are known to have a slow discharge rate. In other words, the power that immediately flows out of the battery is too low. But SABERS researchers have nearly doubled that discharge rate, which means solid-state batteries can actually power larger electronics.

“We have exceeded our target. As we develop further, we can improve this indicator even more, ”said Vigiano. The project’s goals and successes have garnered the attention of companies such as Uber and several other companies interested in building vehicles for future Advanced Air Mobility environments.

The next step for SABERS is to refine the battery design. This will include testing how it performs in practical situations, providing security, and collecting performance data. If successful, the design could be further optimized.

Security, meanwhile, remains the number one issue.

Current research on batteries is mainly focused on the automotive industry, whose safety standards are generally less stringent than those required for aviation applications where batteries operate under more stressful conditions.

SABERS wants to help set this new, higher standard for aviation use by proving that safer batteries are technically feasible and cost effective.

What are the requirements for these solid state batteries? Based on an analysis of what might be required to operate a practical electric aircraft, SABERS focused on five aspects: safety, energy density, discharge rate, hull design, and scalability.

Basically, these batteries need to be safe first and foremost. They also need to hold a huge amount of energy and radiate it efficiently. They also need to be thin and compact and designed with as much detail and care as possible.

Ultimately SABERS is looking at the feasibility of creating safe batteries for electric aircraft. If successful, these innovations could help usher in a new era of energy storage for future air travel.

SABERS is part of the Convergent Aeronautics Solutions project, which aims to provide NASA researchers with the resources they need to determine if their ideas are feasible to solve some of aviation’s biggest technical challenges and perhaps deserve additional efforts at NASA or in the industry.

A two-year event was chosen that began on October 1, 2019, with breaks in the pursuit due to COVID-19 a pandemic could lead to an extension, although nothing has been decided yet.

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Harvesting energy from radio waves to power wearable electronic devices



Flexible Self Powered Electronics

An international team of researchers led by Huanyu “Larry” Cheng, Dorothy Quiggle’s career development professor at the Pennsylvania Department of Engineering and Mechanics, has developed a stretchable antenna and rectenna system that harvests energy from radio waves in the environment to generate energy for wearable devices. Credit: Larry Cheng, PA.

Radio waves entering the environment, from microwaves to Wi-Fi connections, are not only signals of energy consumption, but are also energy sources themselves. An international team of researchers led by Huanyu “Larry” Cheng, Dorothy Quiggle’s career development professor at the Pennsylvania Department of Engineering and Mechanics, has developed a way to harvest radio wave energy to power wearable devices.

Researchers recently published their method in Materials Today Physics.

Current sources of energy for wearable health monitoring devices have their place in powering sensory devices, Cheng said, but each has its own drawbacks. For example, solar energy can only harvest energy when exposed to the sun. A self-powered triboelectric device can only collect energy when the body is in motion.

“We do not want to replace any of these current energy sources,” Cheng said. “We are trying to provide additional permanent energy.”

Researchers have developed a stretchable broadband dipole antenna system capable of wirelessly transmitting data from health monitoring sensors. The system consists of two expandable metal antennas embedded in the conductive graphene metal coated material. The system’s broadband design allows it to maintain its frequency functions even when stretched, bent and twisted. This system is then connected to a stretchable rectifier circuit, creating a rectified antenna, or “rectenna,” capable of converting electromagnetic wave energy into electricity. This electricity can be used to power wireless devices or to charge energy storage devices such as batteries and supercapacitors.

This rectenna can convert radio or electromagnetic waves from the environment into energy to power sensor modules on the device that pulse temperature, hydration, and oxygen levels. Compared to other sources, less power is generated, but the system can generate power continuously, which Cheng says is a significant advantage.

“We use the energy that already surrounds us – radio waves are everywhere and always,” Cheng said. “If we don’t use this environmental energy, it will be wasted. We can collect this energy and transform it into strength. “

Cheng said this technology is a building block for him and his team. Combining it with their new wireless communication device will provide a critical component that will work with existing command sensor modules.

“Our next steps will be to investigate miniature versions of these circuits and work to improve the extensibility of the rectifier,” Cheng said. “This is a platform on which we can easily combine and apply this technology with other modules that we have created in the past. It is easy to extend or adapt for other applications, and we plan to explore these possibilities. “

Link: Stretchable broadband dipole antennas and rectennas for collecting RF energy, by:
Jia Zhu, Zhihui Hu, Chaoyun Song, Ning Yi, Zhaozheng Yu, Zhendong Liu, Shangbin Liu, Mengjun Wang, Michael Gregory Dexheimer, Jian Yang and Huanyu Cheng, March 5, 2021, Materials Today Physics
DOI: 10.1016 / j.mtphys.2021.100377

This article was co-authored by Jia Zhu, who received his Ph.D. in Engineering and Mechanics from Pennsylvania State University in 2020; Zhihui Hu, former visiting professor of engineering and mechanics at the University of Pennsylvania and current associate professor at Wuhan University of Technology in China; Chaoyun Song, Assistant Professor in the Faculty of Engineering and Physical Sciences, Heriot-Watt University in Scotland; Ning Yi, who received her PhD in Engineering and Mechanics from Pennsylvania State University in 2020; Zhaozheng Yu, who received his MS in Engineering and Mechanics from Pennsylvania State University in 2019; Zhendong Liu, Former Visiting Graduate Student, Department of Engineering and Mechanics, University of Pennsylvania; Shangbin Liu, Graduate Student, Department of Engineering and Mechanics, University of Pennsylvania; Mengjun Wang, assistant professor at the School of Electronics and Computer Science, Hebei University of Technology in China; Michael Gregory Dexheimer, who received his MS in Engineering and Mechanics from Pennsylvania State University in 2020; and Jian Yang, professor of biomedical engineering in Pennsylvania.

Support for this work was provided by the National Science Foundation; National Heart, Lung, and Blood Institute, National Institutes of Health; and Penn State.

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Breakthrough in new materials could be the key to revolutionary transparent electronics



Flexible, Transparent Electronics


The optical transparency of the new materials can enable futuristic, flexible and transparent electronics. Credit: RMIT University.

Filling a critical gap in the material spectrum

A new study published this week could pave the way for the next generation of transparent electronics.

Such transparent devices could potentially be embedded in glass, flexible displays, and smart contact lenses to bring futuristic, sci-fi-like devices to life.

For several decades, researchers have been looking for a new class of electronics based on semiconductor oxides, the optical transparency of which could allow this fully transparent electronics to be used.

Oxide devices can also find applications in power electronics and communications technology, reducing the carbon footprint of our utilities.

A team led by RMIT has introduced ultrafine beta-tellurite in a family of two-dimensional (2D) semiconductor materials, providing an answer to this long-term search for a highly mobile p-type oxide.

“This new, highly mobile p-type oxide fills a critical gap in the material spectrum, enabling fast and transparent circuits,” says Team Leader Dr. Torben Daenecke, who led the collaborative work on the three FLEET nodes.

Other key advantages of long-sought oxide-based semiconductors are their stability in air, less stringent purity requirements, low cost, and ease of deposition.

“The missing link in our advance was finding the right, ‘positive’ approach,” says Torben.

Positivity was lacking

There are two types of semiconductor materials. “N-type” materials contain a large number of negatively charged electrons, while “p-type” semiconductors contain many positively charged holes.

It is the amalgamation of n-type and p-type complementary materials that allows electronic devices such as diodes, rectifiers, and logic circuits to be created.

Deposition of molten metal

The molten mixture of tellurium and selenium, rolled over the surface, precipitates an atomically thin sheet of beta-tellurite. Credit: FLEET

Modern life is critically dependent on these materials as they are the building blocks of every computer and smartphone.

An obstacle to oxide devices has been that although many high performance n-type oxides are known, there is a significant lack of high quality p-type oxides.

Theory prompts action

However, in 2018, a computational study found that beta tellurite (β-TeO2) could be an attractive candidate for p-type oxide, with tellurium’s special place on the periodic table means it can behave as a metal or non-metal, providing it oxide with unique beneficial properties.

“This prediction prompted our team at RMIT University to study its properties and applications,” says Dr. Torben Daenecke, FLEET associate researcher.

Liquid metal – the way to explore 2D materials

Dr. Daenecke’s team demonstrated the separation of beta-tellurite using a specially developed synthesis technology based on liquid metal chemistry.

“A molten mixture of tellurium (Te) and selenium (Se) is prepared and allowed to roll on the surface,” explains one of the authors of the article, Patjari Aukaraserinont.

“Due to the presence of oxygen in the ambient air, the melt drop naturally forms a thin surface oxide layer of beta-tellurite. When a drop of liquid rolls over the surface, this oxide layer sticks to it, depositing atomically thin sheets of oxide on its way. “

“The process is similar to drawing: you use a glass rod as a pen, and liquid metal is your ink,” explains Ms. Aucaraserenont, FLEET PhD student at RMIT.

Ali Zawabeti, Patjari Aukaraserinont and Torben Daeneke

RMIT Team (from left to right): Ali Zawabeti, Patjari Aukaraserinont and Torben Daeneke with transparent electronics. Credit: FLEET

While the desired β-phase of tellurite rises below 300 ° C, pure tellurium has a high melting point, above 500 ° C. Therefore, selenium was added to develop alloy which has a lower melting point, which makes synthesis possible.

“The ultra-thin sheets we got are only 1.5 nanometers thick, which equates to just a few atoms. The material was very transparent in the visible spectrum with a band gap of 3.7 eV, which means they are virtually invisible to the human eye, ”explains co-author Dr. Ali Zawabeti.

Beta Tellurite Evaluation: Up to 100X Faster

To evaluate the electronic properties of the developed materials, field effect transistors (FET) were manufactured.

“These devices showed characteristic p-type switching as well as high hole mobility (about 140 cm2V-1s-1), showing that beta-tellurite is ten to one hundred times faster than existing p-type oxide semiconductors. The excellent on / off ratio (over 106) also proves that this material is suitable for energy efficient and fast devices, ”said Ms. Patjari Aukaraserinont.

“The findings fill a major gap in the digital library of materials,” said Dr. Ali Zawabeti.

“Having a fast transparent p-type semiconductor at our disposal could revolutionize transparent electronics, as well as improve displays and improve energy efficient devices.”

The team plans to further explore the potential of this new semiconductor. “Our further research into this exciting material will focus on integration into existing and next generation consumer electronics,” says Dr. Torben Daenecke.

Link: “Highly mobile semiconductor two-dimensional β-TeO2 p-type” April 5, 2021, Nature Electronics
DOI: 10.1038 / s41928-021-00561-5

FLEET researchers from RMIT, ANU and UNSW collaborated with colleagues from Deakin University and the University of Melbourne. Matthias Wurdak of FLEET (ANU) conducted 2D nanosheets transfer experiments, and Kurosh Kalantarzade (UNSW) helped with material and device characteristics analysis.

This project was supported by the Australian Research Council (Center of Excellence and DECRA programs), the authors also acknowledge support from the RMIT University Microscopy and Microanalysis Foundation (RMMF), RMIT University Micronano-Nanotechnology Research Center (MNRF), and funding obtained through postdoctoral MacKenzie program. University of Melbourne Scholarship Program.

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Terahertz image of graphene paves the way for optimization and industrialization



Terahertz image of graphene paves the way for optimization and industrialization

Graphene Flagship researchers have developed a new measurement standard for the analysis of graphene and layered materials that can speed up production and optimize device fabrication. Credit: Graphene Flagship.

Graphene Flagship Researchers Develop a New Measurement Standard for Analysis graphene and multilayer materials that can speed up production and optimize device fabrication.

X-ray scans have revolutionized medical treatment by allowing us to see a person from the inside without surgery. Likewise, terahertz spectroscopy penetrates graphene films, allowing scientists to draw detailed maps of their electrical quality without damaging or contaminating the material. Graphene Flagship has brought together researchers from academia and industry to develop and refine this analytical method, and a new measurement tool is now ready to characterize graphene.

These efforts were made possible by a collaborative environment created by the European consortium Graphene Flagship, with the participation of scientists from Graphene Flagship partners, DTU, Denmark, IIT, Italy, Aalto University, Finland, AIXTRON, UK, imec, Belgium, Graphenea, Spain, University of Warsaw, Poland, and Thales R&T, France, as well as employees in China, Korea and the USA.

Graphene is often sandwiched between many different layers and materials used in electronic and photonic devices. This complicates the quality assessment process. Terahertz spectroscopy simplifies the task. It displays encapsulated materials and shows the quality of the graphene underneath, exposing flaws at critical points in the manufacturing process. It is a fast, non-destructive technology that explores the electrical properties of graphene and laminates without the need for direct contact.

The development of characterization techniques such as terahertz spectroscopy is fundamental to accelerating large-scale production as they ensure that graphene devices are produced consistently and predictably, without drawbacks. Quality control precedes trust. With other developments pioneered by Graphene Flagship, such as roll-to-roll graphene and laminates, fabrication technology is poised to take the next step. Terahertz spectroscopy allows us to ramp up graphene production without losing quality.

Terahertz image of graphene opens the way to industrialization

Terahertz spectroscopy penetrates graphene films, allowing scientists to draw detailed maps of their electrical quality without damaging or contaminating the material. Credit: Peter Baggild (Graphene Flagship / DTU)

“This is the method we need to meet the high performance production levels provided by Graphene Flagship,” explains Peter Baggild of DTU, Graphene Flagship partner. “We are confident that terahertz spectroscopy in graphene production will become as routine an X-ray scan in hospitals,” he adds. “In fact, thanks to terahertz spectroscopy, you can easily map even meter-scale samples of graphene without touching them, which is not possible with some other modern methods.” In addition, Graphene Flagship is currently exploring how to apply terahertz spectroscopy directly to graphene roll-to-roll production lines and accelerate imaging.

Collaboration was key to this achievement. Graphene Flagship researchers in academia have worked closely with leading graphene manufacturers such as Graphene Flagship partners AIXTRON, Graphenea, and IMEC. “This is the best way to ensure that our solution is relevant to our end users, companies that produce graphene and laminates on an industrial scale,” says Böggild. “Our publication is a comprehensive case study that highlights the versatility and reliability of terahertz spectroscopy for quality control and should help our colleagues apply this technique to many industrially important substrates such as silicon, sapphire, silicon carbide and polymers.” he adds.

Setting standards is an important step in the development of any new material to ensure that it is safe, authentic, and offers reliable and consistent performance. This is why Graphene Flagship has a dedicated working group dedicated to graphene standardization, measurement and analytical methods, and manufacturing processes. The newly developed terahertz spectroscopy method will soon become a standard technical specification thanks to the work of the Flagship Committee on Graphene Standardization. “This will undoubtedly accelerate the adoption of this new technology as it will show how the analysis and comparison of graphene samples can be performed in a reproducible manner,” explains Peter Jepsen of Graphene Flagship Partner DTU, co-author of the study. “Terahertz spectroscopy is another step towards increasing confidence in products containing graphene,” he concludes.

Amaya Zurutuza, article co-author and scientific director of Graphene Flagship, a Graphenea partner, says: “At Graphenea, we are convinced that terahertz imaging can help develop quality control methods that can meet manufacturing requirements and provide relevant information on graphene quality. what is needed on our way to the successful industrialization of graphene. “

Turid Gspann, Chair of the Flagship Graphene Standardization Committee, says: “This terahertz [spectroscopy] It is expected that this technology will become widespread in industry. It does not require any special sample preparation and is a mapping method that allows you to analyze large areas with a minimum of time. “

Marco Romagnoli, Head of Electronics and Photonics Integration, Graphene Flagship, adds: “The THz Spectroscopy Instrument for wafer scale applications is a state of the art high TRL system for characterizing multilayer stacks on wafers containing CVD graphene. Works in a short time and with good accuracy, and provides the main parameters of interest such as carrier mobility, conductivity, scattering time, and carrier density. This valuable technical achievement also exemplifies the benefits of being part of a large collaborative project such as the Graphene Flagship. “

Andrea C. Ferrari, Graphene Flagship Science and Technology Officer and Chair of its Management Group, adds: “Once again, Graphene Flagship researchers are pioneering new characterization techniques to drive the development of graphene technology. This helps us move steadily along our innovation and technology roadmap and will drive the commercialization of graphene in a wide range of applications. ”

Reference: “Case Studies of the Electrical Characteristics of Graphene Using Terahertz Time Domain Spectroscopy” by Patrick R. Welan, Bingbin Zhou, Odile Bezensnet, Abhaya Shivayogimatha, Niraja Mishra, Qian Shen, Bjarke S. Jessen, Iwona Pasternak, David MA Mackenzie, G.G. , Kunzhi Sun, Pierre Seneor, Bruno Dlubak, Birong Luo, Frederic Vosterberg, Depin Huang, Haofei Shi, Da Luo, Meihui Wang, Rodney Su Ruoff, Ben R. Conran, Clifford McAlees, Cedric Huygebaert, Stephen Brems, Ilarothy J. Attack, Wlodek Strupinski, Dirch H. Petersen, Stephen Forti, Camilla Coletti, Alexander Juvre, Kenneth B.K. Theo, Alba Centeno, Amaya Zurutuza, Pierre Leganier, Peter U Jepsen and Peter Baggild, February 17, 2021, 2D materials
DOI: 10.1088 / 2053-1583 / abdbcb

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